摘要 |
An ethylene-based polymer which is a copolymer obtained fromethylene and a C3 to C10 ±-olefin and satisfies the following requirements (i), (ii), (iii) and (iv) simultaneously provides a blow-molded product and an extrusion-molded product excellent in moldability, mechanical strength and outward appearance. (i) melt flow rate [MFR 2 (g/10 min)] under a loading of 2.16 kg at 190°C is in the range of 0.01 to 10, (ii) melt tension [MT (g)] and the above melt flow rate [MFR 2 (g/10min)] satisfy the following relationship: MT ‰¥ 3.2 × MFR 2 -0.55 , (iii) an activation energy [Ea] of fluidization is less than 30 (KJ/mol), and (iv) swell ratio is 1.36 or more. The ethylene-based polymer of the invention is preferably produced by copolymerizing ethylene with a C3 to C10 ±-olefin, in the presence of a solid catalyst carrying, on (C) a solid carrier, a mixed transition metal compound consisting of (A1) a group 4 transitionmetal compound containing a specific salicyl aldimine ligand and (A2) a group 4 transition metal compound containing a specific cyclopentadienyl ligand and (B) at least one compound selected from (b-1) an organometallic compound, (b-2) an organoaluminum oxy compound, and (b-3) a compound reacting with the transition metal compound to form an ion pair. |
申请人 |
MITSUI CHEMICALS, INC. |
发明人 |
MATSUURA, SADAHIKO;MATSUKAWA, NAOTO;MITANI, MAKOTO;SAITO, JUNJI;FUJITA, TERUNORI;TOHI, YASUSHI;ENDO, KOJI;IWAMASA, KENJI;FUKUSHI, KEIKO |