| 摘要 |
FIELD: industrial organic synthesis. ^ SUBSTANCE: thiolsulfonates of general formula RSO2SR (I), wherein R represents C1-C20-alkyl or benzyl, are prepared by oxidation of thiols RSH (II) or disulfides RSSR (III), wherein R is as above, oxidation being performed with chlorine dioxide at thiol (disulfide)-to-oxidant molar ratio 1:(2-4) at 10-30°C. Products obtained can be used as biologically active substances possessing bactericidal and fungicidal activities. ^ EFFECT: increased yield of thiolsulfonate (to 92%) owing to use of new oxidant for organosulfur compounds. |
