| 摘要 |
A method for economically preparing a mesoporous molecular sieve material through a more simplified preparing process while maintaining structural uniformity of the mesoporous silica material by substituting metal elements within the skeleton of a mesoporous silica material, and a molecular sieve material prepared by the method are provided. A method for preparing a mesoporous molecular sieve material in which metal elements are substituted within a skeleton structure comprises the steps of: (A) dissolving a surfactant into distilled water, dissolving a metal precursor into an acid, and mixing the dissolved solutions with each other; (B) adding a precursor into the mixture obtained in the step(A), neutrally adjusting pH of the mixture, and subjecting the pH adjusted mixture to hydrothermal reaction; (C) filtering, cleaning and drying the material obtained in the step(B); and (D) calcining the material obtained in the step(C) to remove the surfactant from the material, wherein a silica to substituted metal ratio is in a range from 5:1 to 20:1 within the skeleton of a mesoporous silica powder substituted for the metal elements. The metal precursor is at least one selected from the group consisting of titanium alkoxide, titanium sulfate, titanium tetrachloride(TiCl4), zinc tetrachloride(ZnCl4) and zinc acetate. |
