| 摘要 |
The present invention relates to analysis of analytes, such as metals, refractories, and slag, for the content of oxygen or oxides. The present invention aims (1) to accurately separate and analytically determine, without pretreatment of an iron and steel to remove an oxide film as a contaminant formed on the surface of the iron and steel, oxygen derived from the oxide film as the contaminant and oxygen contained in the iron and steel in the form of oxide inclusions, and (2) to accurately and rapidly analyze an analyte for the oxygen content or oxide content for each oxide contained in a very small amount in the analyte. The method for analyzing a metal for oxygen, using inert gas carrying fusion/infrared absorption analysis, comprises the steps of: placing a metal analyte in a graphite crucible; heat-melting the metal analyte; extracting a gas from the melt bath; and analyzing the gas to determine the total oxygen content of the metal in the form of a plurality of separated waves, wherein the metal analyte is heated at a temperature rise rate of not more than 20 DEG C/sec in a period from a starting point A of a first wave to a peak point B of the first wave, held at a constant temperature in a period from the peak point B of the first wave to an end point C of the first wave, and, after the completion of the appearance of the first wave, is heated to melt the metal analyte for further analysis. The method for analyzing an analyte for oxygen or oxide for each oxide, comprising the steps of: heating an analyte in an inert atmosphere; reacting the analyte with a carbon source while regulating the temperature rise rate; extracting a CO gas successively generated as a result of a reaction of oxygen in the analyte with the carbon source into an inert gas stream; successively analyzing the extracted CO gas by infrared absorption to determine the amount of reacted oxygen or evolved CO; detecting a peak corresponding to the amount of reacted oxygen or evolved CO from successively obtained data on the amount of reacted oxygen or evolved CO; carrying out the analysis while reducing the flow rate of the inert gas for each appearance of the detected peak corresponding to the amount of reacted oxygen or evolved CO to accumulate the data on the amount of reacted oxygen or evolved CO in time sequence; and determining the content of oxygen or oxide for each oxide in the analyte from the accumulated data on the amount of reacted oxygen or evolved oxide. <IMAGE> |
