Compounds comprising aldimine groups

摘要

Aldimine-containing compounds (I), are new. Aldimine-containing compounds (I) of formula ([[R 1>-CO-O-CH 2-C(R 2>)(R 3>)-CH=N] m-R 4>-X-Q] p-R 5>-[A] q), are new. R 1>a monovalent 6-30C hydrocarbon optionally having at least a heteroatom, preferably in the form of ether-oxygen or a ketone-substituent of formula (-R 6>-CO-OR 7>); R 6>2-20C bivalent hydrocarbon having optionally at least a heteroatom, preferably in the form of ether-oxygen; R 7>a monovalent 1-20C hydrocarbon; R 2>, R 3>1-12C monovalent hydrocarbon, 4-20C bivalent hydrocarbon (optionally substituted with 5-8C (preferably 6C) carbocyclic); R 4>(m+1)-valent 2-12C hydrocarbon (optionally containing at least a heteroatom, preferably in the form of an ether-oxygen or tertiary amine-nitrogen); X : O, S or N-R 8>; R 8>1-20C univalent hydrocarbon optionally having at least a carbonic acid ester-, nitrile-, nitro-, phosphonic acid ester-, sulfone- or sulfonic acid ester group or an ether-ketone compound of formula (-R 4>-[N-CH-C(R 3>)(R 2>)-O-CO-R 1>] m); A : a reactive group such as a group of formula (-N=C=Y 1>), a group of formula (-Y 3>-CO-C?=C-Z) or (-Y 3>-CO-C(Z)=CH 2), a group of formula (-C(Z)=CH 2), cyclopropane compound of formula (a) or pyrrole-2,5-dione compound of formula (b); Y 1>O or S; Y 2>O, S or N-H; Z : H or CH 3; Y 3>O or NH; R 5>(p+q)-valent organic group (optionally containing heteroatoms), N, NR 14>, O, OC(O)O, Si, P(O)O 3 or SO 2; R 14>1-20C monovalent hydrocarbon; Q : an amine compound of formula (c), alkyl compound of formula (d) or (e), ketone compound of formula (f) or (g), or pyrrolidine-2,5-dione compound of formula (h); dotted lines : a bond to the substituents; either p : 1-6; and q : 0-5; or p+q : 2-6; and m : 1-4. Independent claims are included for: (1) the preparation of (I); (2) a procedure for the hydrolysis of (I); (3) a procedure for cross-linking (I) to yield a product with the value of q that is less than the value of m and p of (I), under the influence of water; and (4) a composition containing (I). [Image] [Image].