| 摘要 |
THE PRESENT INVENTION PROVIDES A PROCESS FOR PRODUCING ACRYLIC ACID, BY WHICH PROCESS THE PROBLEM, SUCH THAT CATALYST PLACED ON THE GAS INLET SIDE DETERIORATES FASTER THAN THAT PLACED ON THE GAS OUTLET SIDE, IS SOLVED, SO THAT THE CATALYST CAN BE USED STABLY FOR A LONG TIME. THE PROCESS FOR PRODUCING ACRYLIC ACID, ACCORDING TO THE PRESENT INVENTION, COMPRISES THE STEP OF CARRYING OUT CATALYTIC GAS PHASE OXIDATION WITH A FIXED-BED SHELL-AND-TUBE REACTOR AS PACKED WITH A CATALYST, WHEREIN: USED AS THE CATALYST IS AN OXIDE SHOWN BY THE FOLLOWING GENERAL FORMULA (I): MoaVbAcBdCeOf (I) (WHEREIN: A SHOWS AT LEAST ONE MEMBER SELECTED FROM THE GROUP CONSISTING OF NIOBIUM AND TUNGSTEN; B SHOWS AT LEAST ONE MEMBER SELECTED FROM THE GROUP CONSISTING OF CHROMIUM, MANGANESE, IRON, COBALT, COPPER, ZINC, AND BISMUTH; C SHOWS AT LEAST ONE MEMBER SELECTED FROM THE GROUP CONSISTING OF PHOSPHORUS, TIN, ANTIMONY, AND TELLURIUM): AND AT LEAST TWO REACTION ZONES AS PROVIDED BY DIVIDING THE INSIDE OF EACH REACTION TUBE IN A DIRECTION OF AN AXIS OF THE TUBE IN THE REACTOR ARE PACKED WITH THE CATALYST SUCH THAT THERE ARE REGULATED THE KIND AND/OR AMOUNT OF THE A COMPONENT AND/OR THE KIND AND/OR AMOUNT OF THE B COMPONENT.
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