SYNTHESIS METHOD FOR A COMPOUND USED TO FORM A SELF-ASSEMBLED MONOLAYER, COMPOUND FOR FORMING A SELF-ASSEMBLED MONOLAYER, AND LAYER STRUCTURE FOR A SEMICONDUCTOR COMPONENT

摘要

A synthesis method of a compound used to form a self-assembled monolayer used in a semiconductor component is provided. A method includes a first step of replacing a terminal halogen of an omega-haloalk-1-ene with a compound having at least one aromatic group, and a second step of hydrosilylating the reaction product of the first step. Reaction products of the first step include octadec-17-enyloxybenzene, 4-octadec-17''-enyloxy-1,1'-biphenyl, 2-heptadec-16'-enylthiophene, and 2-octadec-17'-enylthiophene. Monolayers provided include 18-phenoxyoctadecyl)trichlorosilane, [18-(1',1''-biphenyl-4'-yloxy)octadecyl]trichlorosilane, (17-thien-2'-ylheptadecyl)trichlorosilane, (18-thien-2'-yloctadecyl)trichlorosilane, and 4-(18'-trichlorosilyloctadecyloxy)benzonitrile. An organic field effect transistor having monolayers according to embodiments of the invention is provided.