摘要 |
The invention relates to electrolyte salts for electrochemical devices of improved physical, chemical and electrochemical stability. The improvement resides in the use of anions of salts of the formula comprising:
i) (B 12 F x Z 12-x ) 2- wherein Z comprises at least one of H, Cl, Br or OR; R comprises at least one of H, alkyl or fluoroalkyl, or at least one polymer and x is at least 3 on an average basis but not more than 12;
ii) ((R'R''R''')NB 12 F x Z (11-x) ) - , wherein N is bonded to B and each of R', R", R''' comprise a member independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, aryl and a polymer; Z comprises H, Cl, Br, or OR, where R comprises H, alkyl or perfluoroalkyl or a polymer, and x is an integer from 0 to 11; or
iii) (R""CB 11 F x Z (11-x) ) - , wherein R"" is bonded to C and comprises a member selected from the group consisting of hydrogen, alkyl, cycloalkyl, aryl, and a polymer, Z comprises H, Cl, Br, or OR, wherein R comprises H, alkyl or perfluoroalkyl or a polymer, and x is an integer from 0 to 11. |
申请人 |
AIR PRODUCTS AND CHEMICALS, INC. |
发明人 |
PEZ, GUIDO PETER;IVANOV, SERGEI VLADIMIROVICH;DANTSIN, GENNADY;CASTEEL, WILLIAM JACK;LEHMANN, JOHN F. |