发明名称 |
Preparation of catalyst and use for high yield conversion of methane to ethylene |
摘要 |
A perovskite catalyst is prepared using a ceramic sol-sol methodology comprising preparing slurry in water of an alkaline earth metal salt, a powdered metal salt and a powdered transition metal oxide, adding a polymeric binder to form a paste, drying and comminuting the paste into a powder and heating the powder with a temperature profile to calcination temperatures. In one embodiment the slurry is formed of titanium oxide with barium carbonate and tin chloride in deionized water, and more specifically by a mixture according to Ba (1-0.05x)+TiO2+SnCl2(0.05x) where x is in moles. The perovskite catalyst is preferably used in a process for oxidative coupling of methane. Catalyst performance is enhanced through the addition of halides to the feed gas in the reaction.
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申请公布号 |
US2007055083(A1) |
申请公布日期 |
2007.03.08 |
申请号 |
US20060594678 |
申请日期 |
2006.11.09 |
申请人 |
BAGHERZADEH EBRAHIM;HASSAN ABBAS;HASSAN AZIZ |
发明人 |
BAGHERZADEH EBRAHIM;HASSAN ABBAS;HASSAN AZIZ |
分类号 |
C07C17/26;B01J21/06;B01J23/00;B01J23/02;B01J23/14;B01J27/08;B01J35/00;B01J37/00;B01J37/08;C01G23/00;C04B35/634;C04B35/636;C07C2/58;C07C2/84 |
主分类号 |
C07C17/26 |
代理机构 |
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地址 |
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