发明名称 PURIFICATION OF BY-PRODUCT STREAM IN PREPARATION OF POLYTRIMETHYLENE TEREPHTHALATE
摘要 A process for preparing polytrimethylene terephthalate from 1,3-propanediol and dimethyl terephthalate in which a carbonyl-containing by-product stream is purified by treatment with an acid catalyst. The polytrimethylene terephthalate preparation process involves reacting 1,3-propanediol and dimethyl terephthalate under esterification reaction conditions and distilling off and condensing by-product methanol and 1,3-propanediol streams containing carbonyl compound s such as acrolein. The condensed by-product stream is treated with an acid catalyst such as an acid ion exchange resin to reduce t he carbonyl content of the stream.
申请公布号 CA2287934(C) 申请公布日期 2007.02.06
申请号 CA19982287934 申请日期 1998.04.29
申请人 SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. 发明人 CHUAH, HOE HIN
分类号 C07C67/03;C08G63/78;C07C69/82;C08G63/183;C08J11/02 主分类号 C07C67/03
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