Dual cure reaction products of self-photoinitiating multifunctional acrylates with thiols and synthetic methods

摘要

Self-photoinitiating liquid oligomeric compositions are disclosed. The oligomeric compositions are formed from multifunctional mercaptans and Michael addition polyacrylate resins, synthesized from multifunctional acrylates and beta-dicarbonyl Michael donors, specifically beta-keto esters, beta-diketones, beta-ketoamides or beta-ketoanilides or combinations thereof The oligomeric compositions are provided along with uses thereof and methods of fabricating.