ISOTACTIC SPECIFIC CATALYST FOR DIRECT PRODUCTION OF HIGHLY ISOTACTIC POLY (PROPYLENE OXIDE) OR HIGHLY ISOTACTIC POLY (BUTYLENE OXIDE)

摘要

(Salph or methoxy salph) Co (initiating ligand) catalyze homopolymerizing rac-PO to produce pure highly isotactic PPO and rac-1-butylene oxide to produce pure isotactic poly(butylene oxide). A product is unfractionated isotactic PPO of m-dyad content > 81%, normally at least 99%.