A protective case of a cellular phone having a luminous layer made of a binder and a phosphor material is provided to radiate light externally through a transparent protection coating layer. A cover layer(11) has a shape to detachably cover a body and cover of a cellular phone, and consists of synthetic resins for the cellular phone. A film layer(12) is formed on an upper surface of the cover layer with plastic resins or reaction hardening resins. A luminous layer(13) is formed on an upper surface of the film layer with binder and luminous material. A protection coating later(14) is formed on an upper surface of the luminous layer with hardening type coating material.