| 摘要 |
This invention relates to a self supporting or substrate-supported film or layer of a photosensitive material comprising a water insoluble complex having one of the following sum formulae (I) to (IV) n R ˆ’ P ˆ’ R €² m ˆ— + m T n ˆ— ˆ’
or m T n ˆ— + n R ˆ’ P ˆ’ R €² m ˆ— ˆ’ n R 1 ˆ’ Q ˆ’ R 1 €² m ˆ— + m T n ˆ— ˆ’
or m T n ˆ— + n R 1 ˆ’ Q ˆ’ R 1 €² m ˆ— ˆ’
wherein
[R-P-R'] and [R 1 -Q-R 1' ] , respectively, are photosensitive tectonic units the photosensitive part of which may undergo a photoreaction, selected from photoisomerizations, photocycloadditions and photoinduced rearrangements, and
wherein P is a group capable of photoisomerization,
Q is a group capable of participating in a photocycloaddition or photoinduced rearrangement reaction, or in a photooxidation reaction,
at least one of R and R' is selected from optionally substituted or functionalized aromatic, preferably aryl-containing groups, and at least one of R and R' is positively or negatively charged, with the proviso that if P is -N=N, R and R' both are independently selected from optionally substituted or functionalised aromatic, preferably aryl-containing groups, and if P has a different meaning, the other of R and R' can alternatively be or contain a straight or branched aliphatic group,
R 1 and R 1' are independently selected either from optionally substituted or functionalized groups, both or at least one of which being an optionally substituted or functionalized aromatic, preferably aryl-containing group while the other alternatively can be or contain a straight or branched aliphatic group, or from such groups which together with Q form an aromatic system, preferably an aryl ring or heteroaryl ring, with the proviso that either at least one of R 1 and R 1' is positively or negatively charged or the ring structure and/or a substituent thereon will carry at least one positive or negative charge,
[T] is an organic, tectonic unit carrying at least one positively or negatively charged group and at least one hydrophobic group, and
m. m*, n and n* are preferably selected from or from about 1, 2, 3, 4, 5, 6, 7 or 8, with the proviso that the values of m and m* are identical or do not differ more than 10% from each other and that the values of n and n* are identical or do not differ more than 10% from each other;
or comprising a mixture of such complexes.
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