发明名称 INJECTION MOLDING METHOD FOR (METH)ACRYLATE COPOLYMERS HAVING TERTIARY AMMONIUM GROUPS
摘要 The invention relates to a method for producing molded bodies by injection molding which comprises the following steps a) melting a (meth)acrylate copolymer that is composed of 30 to 80 % by weight of radically polymerized C1 to C4 alkyl esters of acrylic or methacrylic acid and 70 to 20% by weight of (meth)acrylate monomers with a tertiary ammonium groups in the alkyl group. The (meth)acrylate copolymer used is present in a mixture with 1 to 70% by weight of a softener and a desiccating agent in a ratio of 1: 1 to 1: 20 and with 0.05 to 5 % by weight of a mold-release agent. In addition, other conventional additives or adjuvants and optionally a pharmaceutically active substance can be present in the mixture. Before melting, the mixture has a content of low-boiling components with a vapor pressure of at least 1.9 bar at 120 degrees C of more than 0.5 % by weight. In step b) the mixture is degassed in a thermoplastic state at temperatures of at least 120 degrees C, thereby reducing the content of low boiling components with a vapor pressure of at least 1.9 bar at 120 degrees C to not more than 0.5 % by weight. The molten and degassed mixture is c) injected into the mold cavity of an injection mold, the mold cavity having a temperature that is at least 10 degrees C below the glass transition temperature of the (meth)acrylate copolymer. The molten mixture is then cooled off and the molded body obtained is removed from the mold.
申请公布号 BG64937(B1) 申请公布日期 2006.10.31
申请号 BG20010105657 申请日期 2001.06.28
申请人 ROEHM GMBH & CO. KG 发明人 PETEREIT HANS-ULRICH;BECKERT THOMAS;ASSMUS MANFRED;HOESS WERNER;FUCHS WOLFGANG;SCHIKOWSKY HARTMUT
分类号 A61J3/07;A61K9/48;A61K9/16;A61K9/20;A61K9/22;A61K9/52;A61K9/58;B29D99/00 主分类号 A61J3/07
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