SYNTHETIC CONTROL OF METAL OXIDE NANOCRYSTAL SIZES AND SHAPES

摘要

A general, reproducible, and simple synthetic method that employs readily available chemicals permits control of the size, shape, and size distribution of metal oxide nanocrystals. The synthesis entails reacting a metal fatty acid salt, the corresponding fatty acid, and a hydrocarbon solvent, with the reaction product being pyrolyzed to the metal oxide. Nearly monodisperse oxide nanocrystals of Fe₃O₄, Cr₂O₃, MnO, Co₃O₄, NiO, ZnO, SnO₂, and In₂O₃, in a large size range (3-50 nm), are described. Size and shape control of the nanocrystals is achieved by varying the reactivity and concentration of the precursors.