| 摘要 |
FIELD: organic chemistry. ^ SUBSTANCE: invention relates to method for production of N,N,1-trimethyl-2-(3,4-fullero[60])pyrrolidine amine of formula 1 . ^ Claimed method includes reaction of fullerene[60] (C60) with N,N,N,N-tetramethylmethane diamine of general formula (CH3)2-N-CH2-N-(CH3)2 in C60:(CH3)2-N-CH2-N-(CH3)2 molar ratio of 0.01:(0.01-0.011) in presence of Cp2TiCl2 as catalyst in amount of 15-25 mol.% based on fullerene in argon atmosphere in toluene medium as solvent at 140-160°C for 2-4 hours. Yield of target product is 79-89 %. ^ EFFECT: compound useful as complexing agents, sorbents, biologically active materials and in production of materials with desired electronic, magnetic and optical characteristics. ^ 1 tbl, 1 ex |
