发明名称 OXIRANE COMPOUNDS PREPARING
摘要 FIELD: organic chemistry, chemical technology. ^ SUBSTANCE: invention proposes a method for synthesis of oxirane compounds comprising the following steps: (i) oxidation of alkylaryl to yield alkylaryl hydroperoxide; (ii) contacting at least lesser part of alkylaryl hydroperoxide prepared at the step (i) with olefin in the presence of catalyst to yield oxirane compound and alkylaryl hydroxyl; (iii) separation of oxirane compound from the reaction product from the step (ii), and (iv) contacting at least part of the reaction product no containing oxirane compound with hydrogen to yield alkylaryl and at least of part of the latter is re-circulated to the step (i) and wherein alkylaryl means an alkylaryl compound representing di-(isopropyl)-benzene. Invention provides the possibility for preparing oxirane compound without the necessity for preparing other compounds and reducing the amount of the parent alkylaryl. ^ EFFECT: improved method of synthesis. ^ 3 cl
申请公布号 RU2282624(C2) 申请公布日期 2006.08.27
申请号 RU20030121243 申请日期 2001.12.13
申请人 SHELL INTERNEHSHNL RISERCH MAATSKHAPPIJ B.V. 发明人 MJURREJ BREHNDAN DERMOT;VAPORSIJAN GARO GARBIS
分类号 C07D301/00;C07D301/19;C07B61/00;C07C1/22;C07C15/085;C07D301/14;C07D301/16;C07D303/04;C07D303/12 主分类号 C07D301/00
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