Improvements in and relating to dyestuffs derived from hydrazines

摘要

The invention comprises dyestuffs represented by the formulae in which Ar1 and Ar2 represent two unsubstituted or substituted aryl or arylene nuclei and in the latter case they are connected together by a bridge linkage, R1 represents a hydrogen atom or an alkyl, cyanoalkyl, chloralkyl, hydroxyalkyl or alkoxyalkyl radical and R2 represents a hydrogen atom or an alkyl, cyanoalkyl, chloralkyl, hydroxyalkyl or alkoxyalkyl and, when R1 represents a hydrogen atom or an alkyl group, the phenyl group, x represents a monovalent anion, and B represents a substituted or unsubstituted p-phenylene or 1,4-naphthylene nucleus and a process for the preparation thereof which comprises reacting, at a temperature between 0 DEG and 60 DEG C., an approximately equimolecular mixture of an asymmetric diaryl hydrazine of the general formula and an aromatic amine of the general formula wherein Ar1, Ar2, R1 and R2 have the meanings given above and Z represents a substituted or unsubstituted benzene or naphthalene nucleus with a peroxide, chlorite, ferricyanide, per salt, per acid or dioxide. In examples 1,1-diphenylhydrazine and N-diethylaniline are reacted with per acetic acid (1); N-aminocarbazole is reacted with N-diethylaniline and ammonium persulphate (2); and N1-phenyl-N1 (a -naphthyl)-hydrazine hydrochloride and N-diethylaniline are reacted with manganese dioxide and the product is precipitated with zinc chloride and brine (3). Other hydrazines and coupling compounds are listed. The dyes are suitable for polymers and copolymers of acrylonitrile and dyeing is effected in the presence of a small quantity of a mineral or organic acid optionally with the addition of oxidizing agent, e.g. ammonium persulphate or sodium nitrite.