Anthraquinone dyestuffs

摘要

The invention comprises anthraquinone dyes of the general formula in which X is a halogen atom or an alkyl, hydroxyalkyl, alkoxy, hydroxyalkoxy, or alkylmercapto radical, R is a substituted or unsubstituted aryl radical and n has the values 0, 1, 2 or 3. The dyes may be made by reacting 1 - amino - 4 - aryl - sulphonamido - anthraquinones having exchangeable groups in the 2-position, e.g. sulphonic acid or halogen groups, with substituted or unsubstituted phenols, or by reacting 1,4 - diamino - 2 - phenoxy-anthraquinones with aryl-sulphohalides. R above is preferably a p-toluyl radical. The reaction using phenols is generally effected in the presence of a strong alkali, e.g. potassium or sodium hydroxides or carbonates and at temperatures of 100-180 DEG C. whilst the reaction employing sulphohalides, especially chloro and bromo derivatives, is effected in a solvent at 100-150 DEG C. optionally in the presence of an acid binding agent, solvents referred to being toluene, chlorobenzene, nitrobenzene, pyridine and dioxan. The following compounds as well as the general class of compounds above are claimed per se. 1 - amino - 2 - phenoxy - 4-p - toluene - sulphonamido - anthraquinone; 1 - amino - 2 - (41 - methoxy - phenoxy) - 4 - p-toluene - sulphonamido - anthraquinone; 1-amino - 2 - (31 - chlorophenoxy) - 4 - p - toluene-sulphonamido anthraquinone; 1 - amino - 2-phenoxy - 4 - p - chlorobenzene - sulphonamido - anthraquinone; 1 - amino - 2 - phenoxy-4 - (31,41 - dichlorobenzene -sulphonamido-anthraquinone; 1 - amino - 2 - phenoxy - 4-p - nitrobenzene - sulphonamido - anthraquinone; 1 - amino - 2 - phenoxy - 4 - (31-nitrobenzene - sulphonamido) - anthraquinone; 1 - amino - 2 - phenoxy - 4 - benzene - sulphonamido - anthraquinone; 1 - amino - 2 - phenoxy-4 - o - toluene - sulphonamido - anthraquinone; 1 - amino - 2 (41 - methyl-mercapto -phenoxy)-4-p-toluene-sulphonamido-anthraquinone.ALSO:Polyester materials are dyed using dyes of general formula in which X is halogen, alkyl, hydroxyalkyl, alkoxy, hydroxyalkoxy, or alkyl mercapto, R is a substituted or unsubstituted aryl group and n has the values O, 1, 2 or 3. The dyeing is effected in the presence of carriers at 100 DEG C. or preferably at 110-130 DEG C. under pressure. The dyes are also suitable for use in the thermosol process by which the dyes are fixed by heating at temperature of about 200 DEG C.