| 摘要 |
1,017,454. Melt-spinning polyolefine compositions. MONTECATINI SOC. GENERALE PER L'INDUSTRIA MINERACI E. CHIMICA. May 14, 1963 [May 18, 1962], No. 19085/63. Heading B5B. Filaments, films &c. are made by meltextruding a composition comprising a polyolefine consisting prevailingly of isotactic macromolecules and from 1 to 25% by weight (based on the weight of the composition) of polyepichlorohydrin. The filaments &c. thus obtained, either before or after being stretched, may be treated with one or more aliphatic, aromatic or heterocyclic amines or imines. Alternatively, the amines or imines may be incorporated in the mixture prior to extrusion. The polyolefines are obtained by low pressure polymerisation with stereospecific catalysts and may be polyethylene, polypropylene, polybutene-1, polypentene-1, poly-4-methylpentene- 1, or polystyrene, polypropylene being preferred. The polyepichlorohydrins are preferably obtained by stereospecific polymerization of epichlorohydrin in the presence of catalytic systems. Examples of these are given. The polymeric mixture may be prepared by mixing the solid polymers or by mixing the polyolefine with a solution of the polyepichlorohydrin in a volatile solvent which is subsequently evaporated off. In the production of filaments from the molten mixtures spinnerets whose holes have a length/diameter ratio greater than 1 are preferably used. Spinning is preferably carried out in an inert gas such as nitrogen. The spinning melt preferably contains a small proportion of a dispersing agent. Examples of these are furnished. The stretching of the filaments may be effected at 80‹ to 150‹ C. at stretch ratios of 2 : 1 to 10 : 1 in steam andthey may thereafter be heat set with free or controlled shrinking at temperatures of 80‹ to 160‹ C. The treatment of the filaments &c. with amines or imines may be carried out at temperatures between room temperature and 10‹ C. below the melting-point of the polymer, and the amines or imines may be in solution with an article : bath ratio of 1 : 10 to 1 : 50. The treatment time may range from 2 seconds to 24 hours. The amine or imine may be ethylene diamine, trimethylene-diamine, diethylene triamine, tetramethylene pentamine, ethyleneimine, polyethyleneimine, p-methandiamine, n-dodecylamine, n-octadecylamine, or piperazine and its derivatives The filaments &c. of the invention may be further treated with reagents which render the modifier component of the filaments completely insoluble in water. Examples of such reagents are mono- or diepoxy compounds, mono- and diisocyanates mono- or dialdehydes, halogens or divinylbenzene. The filaments &c. may be treated with an acid, particularly sulphuric acid. Filaments &c. made according to the invention have improved dyeability.
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