发明名称 Process for producing solvent-soluble polyimide
摘要 In the process of the present invention, a solvent-soluble polyimide is produced by polycondensing at least one tetracarboxylic acid component with at least one diamine component in a solvent in the presence of a tertiary amine. The tetracarboxylic acid component is selected from the group consisting of tetracarboxylic dianhydrides represented by the following formula 1: wherein R is as defined in the specification, and tetracarboxylic acids and their derivatives represented by the following formula 2: wherein R and Y<SUP>1 </SUP>to Y<SUP>4 </SUP>are as defined in the specification. Unlike the conventional techniques using an excessively large amount of a chemical imidation agent such as acetic anhydride and a chemical imidation catalyst such as triethylamine, in the process of the present invention, the solvent-soluble polyimide having a high polymerization degree is easily produced in a solvent with good productivity by using only a catalytic amount of the tertiary amine.
申请公布号 US7078477(B2) 申请公布日期 2006.07.18
申请号 US20040875230 申请日期 2004.06.25
申请人 MITSUBISHI GAS CHEMICAL COMPANY, INC. 发明人 OGURO HIROKI;KIHARA SHUTA;BITO TSUYOSHI
分类号 C08G73/10;C08G69/26 主分类号 C08G73/10
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