发明名称 |
PROCESS FOR PERFORMING AN ISOLATED PD(0) CATALYZED REACTION ELECTROCHEMICALLY ON AN ELECTRODE ARRAY DEVICE |
摘要 |
<p>There is disclosed a process for performing an isolated Pd(0) catalyzed reaction electrochemically on an electrode array device. Preferably the Pd(0) catalyzed reaction is a Heck reaction. Specifically, there is disclosed a process for conducting an isolated Pd(0) catalyzed reaction on a plurality of electrodes, comprising providing an electrode array device having a matrix or coating material over metallic or conductive electrodes surfaces and a plurality of electrodes; providing a solution bathing the electrode array device, wherein the solution comprises a transition metal catalyst and a confining agent; and biasing one or a plurality of electrodes on the electrode array device with a voltage or current to regenerate the transition metal catalyst required for the isolated Pd(0) catalyzed reaction, whereby the confining agent limits diffusion of the transition metal catalyst to a volume surrounding each selected electrode surface.</p> |
申请公布号 |
WO2006074335(A2) |
申请公布日期 |
2006.07.13 |
申请号 |
WO2006US00407 |
申请日期 |
2006.01.07 |
申请人 |
COMBIMATRIX CORPORATION;WASHINGTON UNIVERSITY |
发明人 |
TIAN, JUN;MAURER, KARL;MOELLER, KEVIN, D.;TESFU, EDEN |
分类号 |
C25B1/00 |
主分类号 |
C25B1/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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