发明名称 |
Silica-rich carrier, catalyzer for heterogeneous reactions and method for the production thereof |
摘要 |
A silica-rich support and a catalyst containing the silica-rich support and a catalytic component. The support has a specific structure characterized by a set of claimed physicochemical properties: in the <SUP>29</SUP>Si MAS NMR spectrum the state of silicon is characterized by the presence of lines with chemical shifts -100±3 ppm (line Q<SUP>3</SUP>) and -110±3 ppm (line Q<SUP>4</SUP>), with the ratio of the integral intensities of the lines Q<SUP>3</SUP>/Q<SUP>4 </SUP>of from 0.7 to 1.2 (FIG. 1 ); in the IR spectrum there is an absorption band of hydroxyl groups with the wave number 3620-3650 cm<SUP>-1 </SUP>and half-width 65-75 cm<SUP>-1 </SUP>(FIG. 2 ); the carrier has a specific surface area, as measured by the BET techniques from the thermal desorption of argon, S<SUB>AR</SUB>=0.5-30 m<SUP>2</SUP>/g and the surface, as measured by alkali titration techniques, S<SUB>Na</SUB>=10-250 m<SUP>2</SUP>/g, with S<SUB>Na</SUB>/S<SUB>Ar</SUB>=5-30.
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申请公布号 |
US7060651(B2) |
申请公布日期 |
2006.06.13 |
申请号 |
US20020169185 |
申请日期 |
2002.06.27 |
申请人 |
ZAKRYTOE AKTSIONERNOE OBSCHESTVO "KHOLDINGOVAYA KATALIZATORNAYA KOMPANIA" |
发明人 |
BARELKO VIKTOR VLADIMIROVICH;BALZHINIMAEV BAIR SYDYPOVICH;KILDYASHEV SERGEI PETROVICH;MAKARENKO MIKHAIL GRIGORIEVICH;PARFENOV ANATOLY NIKOLAEVICH;SIMONOVA LJUDMILA GRIGORIEVNA;TOKTAREV ALEXANDR VIKTOROVICH |
分类号 |
B01J21/08;B01J21/12;B01J21/14;B01J23/00;B01J23/32;B01J23/38;B01J23/40;B01J23/42;B01J23/44;B01J23/50;B01J23/56;B01J23/58;B01J23/652;B01J23/68;B01J23/70;B01J23/72;B01J23/745;B01J23/755;B01J23/86;B01J23/89;B01J32/00;B01J35/06;B01J35/10;B01J37/02;C01B33/12;C01B33/26;C07B61/00;C07C2/58;C07C9/16 |
主分类号 |
B01J21/08 |
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