发明名称 |
METHOD FOR SOLID PHASE POLYMERIZATION |
摘要 |
An improved method for increasing the relative viscosity and molecular weight of a polyamide polymer (such as nylon 6,6, nylon 6, and the like) while in the solid state involving the use of a phosphorus-containing catalyst (such as 2(2'-pyrydyl)ethyl phosphonic acid, sodium hypophosphite, tolyl phosphinate and manganese hypophosphite or the like) in combination with an oxygen free gas characterized by a low dew point (typically below 30 .degree.C and preferably below -30 .degree.C). Operational and commercial advantages are derived from the combination of using simultaneously a phosphorus-containing catalyst and the recycle of very low dew point drying gas at lower operating temperatures than previously employed in conducting solid phase polymerization of polyamide polymer. Such a process is of particular value during the production of terpolyamide and multipolyamide polymer intended for use in colored nylon fiber manufacture.
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申请公布号 |
CA2268127(C) |
申请公布日期 |
2006.05.23 |
申请号 |
CA19972268127 |
申请日期 |
1997.11.25 |
申请人 |
E.I. DU PONT DE NEMOURS AND COMPANY |
发明人 |
RAMDAS, DUJARI;CRAMER, GREGORY D.;MARKS, DAVID NEIL |
分类号 |
C08G69/06;C08G69/30 |
主分类号 |
C08G69/06 |
代理机构 |
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