VOLUME COMPENSATION IN VAPOUR SORPTION SYSTEMS

摘要

1,200,806. Separating vapours from gases. CONTINENTAL OIL CO. 9 Feb., 1968 [23 Feb., 1967], No. 6595/68. Addition to 1.112,580. Heading B1L. The closed-circuit heated gas regeneration system for the adsorption apparatus of the main Specification, which comprises "compensators" whose heat capacity and volume are each substantially equal to those of each of the beds is modified to provide greater flexibility. The Figure illustrates an apparatus for the separation of vapourised condensables such as gasoline hydrocarbons and water vapour from natural gas. Gas from line 1 enters adsorber 4, 5, or 6 by line 2, 2A, or 2B respectively and leaves depleted or sorbed condensables by lines 7, 7A, or 7B respectively and line 3. Regneration gas from heater 23 and line 8 passes to one of the adsorbers via lines 9, 9A, or 9B respectively and leaves via lines 10, 10A, or 10B and line 11, from which passes to coolers 14 and 15 and scrubber 16, from which liquids are removed by line 17. Regeneration gas from scrubber 16 now passes by line 18, and lines 19 or 19A to compensator 20 or 21, from which it leaves by lines 33 or 31 to line 22 and heater 23. Cooling gas leaves one of the compensators by lines 35 or 32, line 34 and a number of options are then available. In one, gas flow is through line 57, booster 61, line 58, cooler 62 and line 24 back to a hot adsorber 4, 5 or 6 through line 26, 26A or 26B. The gas displaced leaves by line 10, 10A or 10B, lines 13, 55, 56 and 19 or 19A to compensator 20 or 21, and thence by line 22 back to heater 23, whence it passes back to another of the adsorbers to displace lean gas contained therein through residue line 3. At the same time cooling gas leaving another adsorber is being returned to compensators 20 or 21 by lines 27, 27A, or 27B, 28, and 30 or 30A. Other options available are (a) to bypass the heated compensator during the displacement phase by means of line 60, (b) to bypass the volume compensator near the end of the cooling phase to prevent loss of the heat thereof to the cooling gas, and (c) to bypass coolers 14, 15, scrubber 16 and booster 64 during the displacement phase. With such a system, at the end of the desorption phase, the adsorber so treated is hot while the corresponding compensator is cool, and after cooling an adsorber the corresponding compensator is hot. The adsorbent specified in the example is active carbon while the compensators are filled with volcanic rock aggregate. During regeneration, vapours of light hydrocarbons are first displaced from the adsorbent, and so the volume of gas in the regeneration circuit first increases and then decreases. This may be compensated for by means described in the Specification of the main invention.