NANOSTRUCTURED TITANIUM DIOXIDE MATERIALS HAVING LOW OPTICAL GAP AND PROCESS FOR THE PREPARATION THEREOF
摘要
The invention discloses a simple and economic thermal treatment in air allowing to obtain nanostructured TiO<SUB>2</SUB> film with an optical gap substantially close to 2 eV. This is achieved by the use of a cluster-assembled TiO<SUB>2</SUB> film obtained by supersonic cluster beam deposition. This system is characterized by a highly porous and defective structure allowing the efficient incorporation, during thermal treatment, of carbon containing volatile molecules present in air. Substitutional carbon atoms modify the electronic structure of TiO<SUB>2</SUB> nanoparticles, causing the narrowing of the optical gap in the range of visible wavelength. The thermal treatment does not destroy the nanostructure of the as-deposited films.
申请公布号
WO2006002916(A3)
申请公布日期
2006.04.13
申请号
WO2005EP07049
申请日期
2005.06.30
申请人
TETHIS S.R.L.;BARBORINI, EMANUELE;MILANI, PAOLO;PISERI, PAOLO, GIUSEPPE, CARLO
发明人
BARBORINI, EMANUELE;MILANI, PAOLO;PISERI, PAOLO, GIUSEPPE, CARLO