发明名称 1,3-dichloropropene prepn - by thermally dehydrochlorinating 1,2,3-trichloropropane in the presence of oxygen
摘要 <p>(which is the main component of 'D-D', a commercial mixt. also contg. 1,2-dichloropropane, and has activity against insects, fungi and, esp., nematodes while having low phytotoxicity) is produced by thermal dehydrochlorination of 1,2,3-trichloropropane in the gas phase in the presence of free O2 (O2 concn. pref. 5-55, esp. 10-30 mol.%). The presence of free O2 increases the selectivity of the dehydrochlorination reaction, and it also inhibits carbonaceous deposits on the walls of the reaction vessel.</p>
申请公布号 FR2126385(A1) 申请公布日期 1972.10.06
申请号 FR19720006260 申请日期 1972.02.24
申请人 SHELL INTERNA RESE MAAT 发明人
分类号 C07C17/25;(IPC1-7):07C17/00;01N9/00;07C21/00 主分类号 C07C17/25
代理机构 代理人
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