Polyoxometallate catalysts and catalytic processes

摘要

An active and selective hydrocarbon partial oxidation catalyst comprises an activated partially-reduced polyoxometallate, preferably niobium polyoxomolybdate, that is prepared from a suitable polyoxoanion, which has been exchanged with a suitable cation and activated by heating to an activation effective temperature in the presence of a suitable reducing agent such as pyridinium. C₃ and C₄ hydrocarbons may be partially oxidized selectively to acrylic acid and maleic acid.