发明名称 |
Processes for producing (meth)acrylic acid |
摘要 |
In the purification and distillation step of acrylic acid (including (meth)acrylic acid), stable continuous operation for a long period is enabled by inhibiting the undesirable polymerization reaction of acrylic acid thereby to prevent the device from a trouble such as clogging. A process for producing acrylic acid which comprises purifying crude acrylic acid prepared by vapor-phase catalytic oxidation by distillation, wherein the concentration of beta-acryloxypropionic acid in the feed stream to a distillation column mainly for the separation of water from acrylic acid is controlled to be at most one-fiftieth of the concentration of acrylic acid; the concentration of beta-acryloxypropionic acid in the feed stream to a distillation column mainly for the separation of acetic acid from acrylic acid is controlled to be at most one-fortieth of the concentration of acrylic acid; and the concentration of beta-acryloxypropionic acid in the feed stream to a distillation column mainly for the separation of acrylic acid from water, acetic acid and a solvent is controlled to be at most one-fiftieth of the concentration of acrylic acid.
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申请公布号 |
US7015357(B2) |
申请公布日期 |
2006.03.21 |
申请号 |
US20040898341 |
申请日期 |
2004.07.26 |
申请人 |
MITSUBISHI CHEMICAL CORPORATION |
发明人 |
YADA SHUHEI;TAKASAKI KENJI;OGAWA YASUSHI;SUZUKI YOSHIRO |
分类号 |
C07C51/42;C07C51/44;C07C57/02 |
主分类号 |
C07C51/42 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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