发明名称 |
Process for separating mixtures of crude, water-containing amines originating from the amine synthesis |
摘要 |
<p>Separation of mixture of amine(s), water, low-boiling fraction and optionally high-boiling fraction includes optional distillative separation of low and high-boiling fractions, extraction of mixture with aqueous sodium hydroxide solution; and distillation of resultant aqueous-organic phase to recover anhydrous amine(s) from sump or side in separation part of column and amine/water azeotrope. <??>Separation of a mixture containing amine(s) (I), water, low-boiling fraction (II) and optionally high-boiling fraction (III) comprises: <??>(i) optional distillative separation of a first low-boiling fraction; <??>(ii) optional distillative separation of a first high-boiling fraction; <??>(iii) extraction of the mixture with aqueous sodium hydroxide (NaOH) solution, giving a first aqueous phase containing NaOH solution and a second aqueous-organic phase (IV) containing amines, other low-boiling fractions and optionally other high-boiling fractions; and <??>(iv) distillation of the aqueous-organic phase to recover anhydrous amines as sump discharge or side discharge in the separation part of the column, an amine/water azeotrope, which is recycled to (iii), as side discharge in the concentration part and further low-boiling fraction as top discharge.</p> |
申请公布号 |
EP1312599(B1) |
申请公布日期 |
2006.03.08 |
申请号 |
EP20020024433 |
申请日期 |
2002.10.29 |
申请人 |
BASF AKTIENGESELLSCHAFT |
发明人 |
WOELFERT, ANDREAS, DR.;RUETTER, HEINZ, DR.;RITTINGER, STEFAN, DR.;WEHINGER, MARK;ALEMANY, AURELIE;SCHMIDT, WILLI |
分类号 |
C07C209/86;C07D295/00;B01D3/00;B01D3/14;B01D3/36;B01D11/04;C07C209/84;C07C211/04;C07C211/08;C07D207/04;C07D211/04;C07D211/12;C07D265/30;C07D295/02;C07D295/03 |
主分类号 |
C07C209/86 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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