发明名称 |
Preparation of optically active alkyl succinic acid monoalkyl esters comprising enantioselective hydrogenation of ester compound in presence of catalyst, which carries phospholane ligand |
摘要 |
<p>Preparation of optically active alkyl succinic acid monoalkyl esters (I) comprises enantioselective hydrogenation of ester compounds (II) in the presence of a catalyst, which carries a phospholane ligand (L). Preparation of optically active alkyl succinic acid monoalkyl esters of formula (I) comprises enantioselective hydrogenation of ester compound of formula (II) in the presence of a catalyst, which carries a phospholane ligand of formula (L). D, E : H or 1-10C alkyl; R : 1-10C alkyl, aryl or alkylaryl; R 2>1-6C alkyl, aryl or alkylaryl; R 1>H or R 2>; A : R 1>or heterocyclic compound of formula (b); and B1 : bridge member with 1-5C between two P-atom or Cp-Fe-Cp. [Image] [Image].</p> |
申请公布号 |
DE102004032968(A1) |
申请公布日期 |
2006.02.09 |
申请号 |
DE20041032968 |
申请日期 |
2004.07.07 |
申请人 |
BASF AG |
发明人 |
HETTCHE, FRANK;JAEKEL, CHRISTOPH;FRIEDRICH, MARKO;PACIELLO, ROCCO |
分类号 |
B01J31/24;C07C67/303;C07C69/40 |
主分类号 |
B01J31/24 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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