摘要 |
The invention provides a process for preparing linear organopolysiloxanes (P) having diorganosiloxy units and Si-H groups, in which, in a first step, diorganodichlorosilanes (A) and monochlorosilanes (B) and optionally dichlorosilanes (C), at least one of the monochlorosilanes (B) or dichlorosilanes (C) containing Si-H groups, are reacted with at most 0.5 mol of water per mole of hydrolyzable chlorine to give a partial hydrolyzate (T) and gaseous hydrogen chloride, and, in a second step, the SiCl groups still present in the partial hydrolyzate (T) are removed by treating with water to form hydrochloric acid, and a hydrolyzate (H) containing the organopolysiloxanes (P) is obtained.
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