发明名称 PROPYLENE ELASTOMER
摘要 The novel propylene elastomer according to the invention contains (1) units derived from propylene in amounts of 50 to 95 % by mol and units derived from 1-butene in amounts of 5 to 50 % by mol, and has (2) triad tacticity (mm fraction), determined by the 13C-NMR spectrum (hexachlorobutadiene solution, based on tetramethylsilane), of not less than 90 %, (3) an intrinsic viscosity (in decalin at 135 .degree.C) of 0.1 to 12 dl/g, (4) a molecular weight distribution (Mw/Mn) of not more than 3 and (5) a randomness parameter B value of 1.0 to 1.5, preferably 1.0 to 1.3. In addition, the elastomer desirably has properties that (6) the elastomer has a melting point Tm of 60 to 140 .degree.C, and the melting point Tm and a 1-butene constituent unit content M (% by mol) in the elastomer satisfy the relation -2.6M + 130 .ltoreq. Tm .ltoreq. -2.3M + 155, and (7) a crystallinity C of the elastomer measured by X-ray diffractometry and the 1-butene constituent unit content M (a by mol) satisfy the relation C .gtoreq. -1.5M + 75. Such propylene elastomer is excellent in rigidity, heat resistance, scratch resistance, transparency, heat sealing properties and blocking resistance. The propylene elastomer can be prepared using a specific transition metal compound catalyst.
申请公布号 CA2155016(C) 申请公布日期 2005.10.25
申请号 CA19942155016 申请日期 1994.11.29
申请人 MITSUI PETROCHEMICAL INDUSTRIES, LTD. 发明人 UEDA, TAKASHI;MIZUNO, AKIRA;KAWASAKI, MASAAKI;FUKUOKA, DAISUKE;KISO, YOSHIHISA;TANIZAKI, TATSUYA;HASHIMOTO, MIKIO;SUGI, MASAHIRO;TSUTSUI, TOSHIYUKI
分类号 C08F210/06;C08F210/08;(IPC1-7):C08F210/06 主分类号 C08F210/06
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