摘要 |
This abstract discusses producing mixed matrix composite (MMC) membranes with a good balance of permeability and selectivity. MMC membranes are particularly needed for separating fluids in oxygen/nitrogen separation processes, processes for removing carbon dioxide from hydrocarbons or nitrogen, and the separation of hydrogen from petrochemical and oil refining streams. MMC Membranes made using washed sieve material, such as washed SSZ-13 sieve material, provide surprisingly good permeability and selectivity. The method of the current invention produces a fluid separation membrane by providing a polymer and a washed molecular sieve material, then synthesizing a concentrated suspension of a solvent, the polymer, and the washed molecular sieve material. The concentrated suspension is used to form the fluid separation membrane of the desired configuration. Membranes of the current invention can be formed into hollow fiber membranes that are particularly suitable for high trans-membrane pressure applications.
|