| 摘要 |
FIELD: petrochemical processes. ^ SUBSTANCE: tert-butyl alcohol, 4,4-dimethyl-1,3-dioxan and/or formaldehyde are fed into reaction zone in the form of homogenous mixture with recycled aqueous solution of acid catalyst, which mixture is preliminarily prepared in a separate apparatus at heated to 80-90°C and said aqueous acid solution freed of organics is preliminarily passed through cationite at volume flow rate 15-20 h-1. Process is conducted at elevated temperature and pressure exceeding pressure of water steam at this temperature, and at molar excess of tert-butyl alcohol relative to summary amount of formaldehyde in hollow apparatus mounted coaxially over shell-and-tube heat exchanger and provided with circulation pipe connecting top part of hollow apparatus to bottom part of shell-and-tube heat exchanger, diameter of this pipe being at least three times lass than that of hollow reactor. Circulating factor at least 100 h-1 is achieved with the aid of pump installed in feed supply line into bottom part of hollow apparatus. Reaction products and part of aqueous acid solution are removed from the top of hollow apparatus in one stream passed into separator. ^ EFFECT: simplified technology and increased yield of isoprene. ^ 1 dwg, 3 tbl, 3 ex |
