| 摘要 |
THE INVENTION PROVIDES A PROCESS WHICH, IN PRODUCING ACRYLIC ACID THROUGH VAPOR-PHASE CATALYTIC OXIDATION OF ACROLEIN-CONTAINING GAS USING A SHELL-AND-TUBE TYPE FIXED BED REACTOR, CAN EFFECTIVELY INHIBIT OCCURRENCE OF HOT SPOTS AND PRODUCE ACRYLIC ACID AT HIGH YIELDS. SAID PROCESS IS CHARACTERIZED BY DIVIDING EACH OF THE REACTION TUBES INTO AT LEAST THREE REACTION ZONES IN ITS AXIAL DIRECTION, FILLING THE FIRST REACTION ZONE CLOSEST TO THE GAS INLET WITH A CATALYST HAVING A HIGHER ACTIVITY THAN THAT OF THE CATALYST FILLING THE ADJACENT, SECOND REACTION ZONE AND FILLING THE SUBSEQUENT REACTION ZONES WITH CATALYSTS OF DIFFERENT ACTIVITY LEVELS SUCH THAT THE CATALYTIC ACTIVITY SUCCESSIVELY RISES FROM THE SECOND REACTION ZONE TOWARD THE GAS OUTLET SIDE.
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