发明名称 СНИЖЕНИЕ ВЯЗКОСТИ РЕАКЦИОННОСПОСОБНЫХ ТЯЖЕЛЫХ ПОБОЧНЫХ ПРОДУКТОВ ВО ВРЕМЯ ПОЛУЧЕНИЯ 1,3-ПРОПАНДИОЛА
摘要 The present invention is an improvement upon the process for the production of 1,3-propanediol wherein an aqueous solution of 3-hydroxy propanal is formed, catalyst, if any, used in said formation is removed from the solution, sodium hydroxide is added to the solution to neutralize any acid therein such that the pH is at least about 5, the neutralized aqueous solution is subjected to hydrogenation to produce a crude 1,3-propanediol mixture which is distilled to produce 1,3-propanediol, water, and reactive heavy components. The improvement on this process comprises replacing the sodium hydroxide with a hydroxide selected from the group consisting of ammonium hydroxide, alkali metal hydroxides other than sodium hydroxide, and alkaline earth metal hydroxides to reduce the viscosity of the reactive heavy components.
申请公布号 RU2005113297(A) 申请公布日期 2005.09.20
申请号 RU20050113297 申请日期 2003.10.02
申请人 ШЕЛЛ ИНТЕРНЭШНЛ РИСЕРЧ МААТСХАППИЙ Б.В. (NL) 发明人 ДЖЕЙМС Толмадж Гейл (US);КОМПЛИН Гленн Чарльз (US);НИЛЬСЕН Эдвард Льюис (US);НИФТОН Джон Фредерик (US);ПАУЭЛЛ Джозеф Браун (US);ВЕЙДЕР Пол Ричард (US)
分类号 C07C29/14;C07C29/141;C07C45/58 主分类号 C07C29/14
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