摘要 |
The invention concerns a novel crystalline solid UVL-1 which has an X ray diffraction diagram containing at least the following characteristic peaks: <tables id="TABLE-US-00001" num="1"> <table frame="none" colsep="0" rowsep="0"> <tgroup align="left" colsep="0" rowsep="0" cols="3"> <colspec colname="1" colwidth="91PT" align="center"/> <colspec colname="2" colwidth="35PT" align="center"/> <colspec colname="3" colwidth="91PT" align="center"/> <THEAD> <ROW> <ENTRY/> </ROW> <ROW> <entry namest="1" nameend="3" align="center" rowsep="1"/> </ROW> <ROW> <ENTRY>d<SUB>hkl </SUB>(A)</ENTRY> <ENTRY>2theta (°)</ENTRY> <ENTRY>I/I<SUB>0</SUB></ENTRY> </ROW> <ROW> <entry namest="1" nameend="3" align="center" rowsep="1"/> </ROW> </THEAD> <TBODY VALIGN="TOP"> <ROW> <ENTRY/> </ROW> </TBODY> </TGROUP> <tgroup align="left" colsep="0" rowsep="0" cols="3"> <colspec colname="1" colwidth="91PT" align="char" char="."/> <colspec colname="2" colwidth="35PT" align="char" char="."/> <colspec colname="3" colwidth="91PT" align="center"/> <TBODY VALIGN="TOP"> <ROW> <ENTRY>11.69</ENTRY> <ENTRY>7.55</ENTRY> <ENTRY>mw to vs</ENTRY> </ROW> <ROW> <ENTRY>7.50</ENTRY> <ENTRY>11.79</ENTRY> <ENTRY>vw to w</ENTRY> </ROW> <ROW> <ENTRY>5.76</ENTRY> <ENTRY>15.36</ENTRY> <ENTRY>w to mw</ENTRY> </ROW> <ROW> <ENTRY>3.70</ENTRY> <ENTRY>24.00</ENTRY> <ENTRY>m to s</ENTRY> </ROW> <ROW> <ENTRY>3.57</ENTRY> <ENTRY>24.91</ENTRY> <ENTRY>s</ENTRY> </ROW> <ROW> <ENTRY>3.36</ENTRY> <ENTRY>26.49</ENTRY> <ENTRY>vs</ENTRY> </ROW> <ROW> <ENTRY>3.14</ENTRY> <ENTRY>28.48</ENTRY> <ENTRY>w to mw</ENTRY> </ROW> <ROW> <ENTRY>2.50</ENTRY> <ENTRY>35.88</ENTRY> <ENTRY>vw</ENTRY> </ROW> <ROW> <ENTRY>2.41</ENTRY> <ENTRY>37.30</ENTRY> <ENTRY>vw</ENTRY> </ROW> <ROW> <entry namest="1" nameend="3" align="center" rowsep="1"/> </ROW> </TBODY> </TGROUP> </TABLE> </TABLES> and with a chemical composition, expressed as the anhydrous compound, in terms of moles of oxide: (XO<SUB>2</SUB>):(Y<SUB>2</SUB>O<SUB>3</SUB>)<SUB>m</SUB>:(Z<SUB>2/n</SUB>O)<SUB>p </SUB> in which: X represents at least one tetravalent element selected from the group formed by Si, Ge; Y represents at least one trivalent element selected from Al, B, Cr, Ga; Z represents at least one cation with valency n; and in which: n is in the range 2 to 4, m is in the range 0 to 0.2, preferably in the range 0 to 0.05, and p is in the range 0 to 0.2, preferably in the range 0 to 0.05. The invention also concerns a hydrocracking/hydroconversion process and a hydrorefining process employing said solid in the catalyst composition.
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