Mehrstufige Lösungsmittelextraktion von Metallen

摘要

Proposed is an improvement in a multi-stage solvent extraction process of a metal value such as rare earth elements from an acidic feed solution containing the metal value in the form of a water-soluble salt by bringing the aqueous solution into contact with a water-immiscible organic extractant solution containing an extractant compound which releases an acid when combined with the metal ions. While the concentration of the acid in the aqueous feed solution is increased when contacted with the organic extractant solution containing an extractant agent of the above mentioned type so as to cause a shift of the extraction equilibrium unfavorably against further extraction of the metal ions, the acid in the aqueous feed solution prior to contacting with the organic extractant solution in a succeeding stage of extraction is at least partly decreased, instead of the conventional expensive way of neutralization by the addition of an alkaline neutralizing agent to the aqueous solution, by ion exchange dialysis with dialyzing water through an anion exchange membrane.