摘要 |
This invention provides the three novel La,Fe, La,Cr and Sm,Fe substituted barium titanate solid solution ferroelectric compositions with the formula Ba<SUB>1-x</SUB>Ln<SUB>x</SUB>Ti<SUB>1-x</SUB>M<SUB>x</SUB>O<SUB>3 </SUB>wherein when Ln is La, M is Fe or Cr, when Ln is Sm, M is Fe and x is from about 0.02 to about 0.06 and mixtures thereof, the novel La,Fe substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba<SUB>1-y</SUB>Sr<SUB>y</SUB>)<SUB>1-x</SUB>La<SUB>x</SUB>Ti<SUB>1-x</SUB>Fe<SUB>x </SUB>O<SUB>3 </SUB>wherein y is greater than zero and less than about 0.6 and x is from about 0.01 to about 0.06 and the novel La,Al substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba<SUB>1-y</SUB>Sr<SUB>y</SUB>)<SUB>1-x</SUB>La<SUB>x </SUB>Ti<SUB>1-x/4 3a/4</SUB>Al<SUB>a(x-a)/4</SUB>O<SUB>3 </SUB>wherein denotes a vacancy, y is greater than zero and less than about 0.6, a is from about 0.01 to about 0.06 and x is from 0.02 to about 0.10 with the proviso that x is greater than or equal to a. These low loss tunable ferroelectric compositions are especially useful in tunable microwave thin film devices which fall into three types: interdigital and trilayer capacitors, coplanar waveguides and microstrips.
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