摘要 |
<p>Processes are disclosed for preparing a printable and printed articles by coating a substrate with a composition containing a crosslinkable amine functional polymer and a polyfunctional isocyanate blocked by a blocking agent. The coated substrate is heated to a sufficient temperature to deblock the blocked polyfunctional isocyanate and thereby produce a crosslinked hydrophobic, ink receptive polymer layer on the substrate. Printed articles are prepared by forming an image on the crosslinked hydrophobic, ink receptive layer. In a preferred embodiment, the crosslinked hydrophobic, ink receptive polymer composition is characterized by a solvent resistance fraction of at least 0.6 and a solvent absorbance capacity of at least 300. The substrate of the printed article is preferably polymer, metal, glass, or paper, more preferably polymer film. A process for preparing printable articles wherein the substrate is a fluoropolymer is especially preferred.</p> |