Method for determining particle size distribution and structural properties of concentrated dispersions

摘要

A method is described which applies Acoustic Spectrometry to characterize both the particle size distribution and micro-rheological properties of the structured concentrated dispersions. It suggests to model the structured dispersion as a collection of the spherical particles which are connected together with flexible strings. Oscillation of these strings creates an additional energy dissipation which contributes to the total attenuation. This dissipation is dependent on the second virial coefficient characterizing the flexibility of the strings. It is shown that the value of the second virial coefficient can be calculated from the measured attenuation spectra either for known particle size or together with particle size as adjustable parameter.