发明名称 СПОСОБ ПОЛУЧЕНИЯ СВЕТО И ТЕРМОСТАБИЛИЗАТОРА ПОГОДОСТОЙКОГО ПОЛИЭТИЛЕНА
摘要 FIELD: organic chemistry, chemical technology. ^ SUBSTANCE: invention relates to a method for preparing a photo- and thermostabilizer for preparing weatherproof polyethylene. Method for preparing photo- and thermostabilizer involves heating 2-tert.-butylphenol and methanol in autoclave in the presence of alkali and zinc oxide at temperature 220-250°C and prepared product represents a mixture comprising tert.-butylated hydroxy-exo-calyx[4]arenes and methylene-bis-phenols. For stabilizing high density polyethylene the use of a mixture of tert.-butylated hydroxy-exo-calyx[4]arenes and methylene-bis-phenols taken in the amounts 0.25-0.5% is the most effective. Photo- and thermostabilizer are prepared for a single stage by using available taw. Photo- and thermostabilizers of weatherproof polyethylene represents a mixture of tert.-butylated hydroxy-exo-calyx[4]arenes and methylene-bis-phenols and provides more effective photo- and thermostabilization as compared with using individual products as stabilizers. ^ EFFECT: improved preparing method. ^ 2 tbl, 1 dwg
申请公布号 RU2004101592(A) 申请公布日期 2005.06.27
申请号 RU20040101592 申请日期 2004.01.19
申请人 Новосибирский институт органической химии им. Н.Н. Ворожцова СО РАН (НИОХ СО РАН) (RU) 发明人 Крысин Алексей Петрович (RU);Васильев Владимир Геннадьевич (RU);Русов Владимир Павлович (BY);Александрова Тамара Ивановна (BY);Корецка  Людмила Сергеевна (BY);Егорова Тать на Глебовна (RU);Гражданников Александр Евгеньевич (RU)
分类号 C07C39/12;C07C39/16;C08F110/02;C08K5/13 主分类号 C07C39/12
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