| 摘要 |
Reactive dye mixtures (A) consist of naphthyl compound dyes (I), monoazo dyes (15-16) each in an amount of 0-10 wt% and aryl dyes (Ga-Gf) are new. Reactive dye mixtures (A) consist of naphthyl compound dyes of formula (I), monoazo dyes of formula (15-16) each in an amount of 0-10 wt% and aryl dyes of formulae (Ga-Gf) are new. D 1>-D 7>aryl compound of formula (1), naphthyl compound of formula (2), benzene sulfonyl compound of formula (3), benzamide compound of formula (9); R 1>, R 2>, R 3>, R 4>, R 1>3>-R 1>8>H, 1-4C alkyl, 1-4C alkoxy, OH, sulfo, carboxyl, CN, NO 2, amido, ureido or halo; X 1>H or -SO 2-Z; Z : -CH=CH 2, -CH=CH 2CH 2Z 1>or OH; Z 1>OH or alkali-detachable; X 2>X 1>; R 5>, R 6>R 1>and R 2>; R 7>H, optionally substituted 1-4C alkyl, 1-4C alkoxy, sulfo, halo or carboxyl-substituted phenyl; Z 2>pyrimidine compound of formula (4), 1,3,5-triazine compound of formula (5) or benzopyrazine compound of formula (6); V : F or Cl; U 1>, U 2>F, Cl or H; Q 1>, Q 1>Cl, F, cyanamido, OH, 1-6C alkoxy, phenoxy, sulfophenoxy, mercapto, 1-6C alkylmercapto, pyridino, carboxypyridino, carbamoylpyridino, -N(R 8>)-W 1-SO 2Z or -N(R 9>R 1>0>); R 8>H, 1-6C alkyl, sulfo-(1-6C)-alkyl or phenyl (optionally substituted by (1-4C)-alkyl, (1-4C)-alkoxy, sulfo, halo, carboxyl, acetamido or ureido; R 9>, R 1>0>R 8>or combine to form a cyclic ring system of the formula -(CH 2) j- or -(CH 2) 2-E-(CH 2) 2-; j : 4-5; E : O, S, sulfonyl or -NR 1>1>; R 1>1>1-6C alkyl; W 1phenylene (optionally substituted by 1-2 substituents of 1-4C alkyl, 1-4C alkoxy, carboxyl, sulfo, Cl, Br or 1-4C alkylenearylene or 2-6C alkylene, which may be interrupted by O, S, sulfonyl, amino, carbonyl, carboxamido or is phenylene-CONH phenylene (optionally substituted by (1-4C)-alkyl, (1-4C)-alkoxy, OH, sulfo, carboxyl, amido, ureido or halo) or naphthylene (optionally substituted 1-2 sulfo groups); R 1>2>H, 1-4C alkyl, aryl or substituted aryl radical; A : phenylene compound of formula (10), naphtylene compound of formula (11) or -(CR 1>9>R 2>0>)-; k : greater than 1; X 3>X 1>; R*, R** : H, 1-4C alkyl or -CH 2-SO 3M; R 3>1>H, acetyl, carbamoyl, compound (4), (5) or -CH 2-SO 3M; R 3>2>-CH 2-SO 3M; R 3>3>CH 3, carboxyl or carboxyalkyl with 1-4C alkyl; R 3>4>H or CH 3; R 3>5>H, CN, carbamoyl, carboxyl or -CH 2-SO 3M; R 3>6>CH 3, ethyl or beta -sulfoethyl; R 3>7>CH 3, carboxyl or carboxyalkyl with 1-4C alkyl; R 3>8>acetamido, ureido, CH 3or OCH 3; R 3>9>H, CH 3or OCH 3; m : 0-1; n : 1-3; Z 3>Z 2>; and M : H, alkali metal or one equivalent of an alkaline earth metal. H, 1-4C alkyl, 1-4C alkoxy, OH, CN, amido, halo or aryl; [Image] Independent claims are also included for: (1) the aqueous liquid product comprises (A) having total dye content of 5-50 wt%; (2) aqueous printing inks for textile printing by the inkjet process comprising (I) in 0.01-40 wt% based on the total weight of the inks; and (3) process for dyeing, conventionally printing and also inkjet printing textile fiber materials, which comprises utilizing (A). |
