摘要 |
<P>PROBLEM TO BE SOLVED: To provide a simple and new method for preferably stereoselectively producing biphenyl by reacting an aromatic compound having a substituent or substituents to oxidatively dimerize. <P>SOLUTION: The biphenyl is produced by reacting the aromatic compound having a substituent or substituents to oxidatively dimerize by using a catalyst containing a rhodium compound, preferably the rhodium compound and a copper compound in an atmosphere containing molecular oxygen. Especially 2,3,3',4'-biphenyltetracarboxylic acid tetraester is stereoselectively produced from a phthalic acid diester. <P>COPYRIGHT: (C)2005,JPO&NCIPI |