发明名称 METHOD FOR PRODUCING TCD-DIALDEHYDE
摘要 PROBLEM TO BE SOLVED: To provide a simple and economical method for producing 3(4),8(9)-bisformyl-tricyclo[5.2.1.0<SP>2.6</SP>]decane by hydroformylating dicyclopentadiene and then distilling. SOLUTION: This hydroformylation of dicyclopentadiene is performed by 2 steps. In a first hydroformylation step, the reaction is performed in a heterogeneous reaction system by using a compound of a transition metal of group VIII of the periodic table containing a water soluble organic phosphorus (III) compound bonded in a complex state to obtain 8(9)-formyl-tricyclo[5.2.1.0<SP>2.6</SP>]decene-3, and in a second hydroformylation step, thus obtained 8(9)-formyl-tricyclo[5.2.1.0<SP>2.6</SP>]decene-3 is converted into 3(4),8(9)-bisformyl-tricyclo[5.2.1.0<SP>2.6</SP>]decane in a homogeneous organic phase in the presence of a group VIII transition metal compound. COPYRIGHT: (C)2005,JPO&NCIPI
申请公布号 JP2005139181(A) 申请公布日期 2005.06.02
申请号 JP20040321212 申请日期 2004.11.04
申请人 CELANESE CHEMICALS EUROPE GMBH 发明人 LAPPE PETER DR;SPRINGER HELMUT;LUKAS RAINER
分类号 B01J31/24;C07B61/00;C07C45/50;C07C45/82;C07C47/347;C07C47/445;(IPC1-7):C07C45/50 主分类号 B01J31/24
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