发明名称 |
PROCESS FOR PRODUCING 1-OCTENE FROM BUTADIENE IN THE PRESENCE OF TITANIUM CATALYSTS |
摘要 |
A method is described for the preparation of 1-octene starting from butadiene, wherein in a first step (a) the bis-hydrodimerization of butadiene to 1,7-octadiene is effected in the presence of a catalyst based on palladium containing one or more tri-substituted monodentate phosphines, in an aprotic polar solvent, in a second step (b) the partial catalytic hydrogenation of 1,7-octadiene to 1-octene is effected in the presence of a titanium compound activated with one or more metal alkyls of group 13 (selected from boron, aluminum, gallium, indium). |
申请公布号 |
WO2005047218(A1) |
申请公布日期 |
2005.05.26 |
申请号 |
WO2004EP11461 |
申请日期 |
2004.10.11 |
申请人 |
POLIMERI EUROPA S.P.A.;DELLEDONNE, DANIELE;RIVETTI, FRANCO |
发明人 |
DELLEDONNE, DANIELE;RIVETTI, FRANCO |
分类号 |
A01N25/22;A01N43/30;A01N53/00;A23K1/00;A23L1/00;A61K9/00;A61K9/70;B01J31/26;C07C2/38;C07C2/40;C07C5/05;C08B37/16 |
主分类号 |
A01N25/22 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|