MACROMONOMER DERIVED FROM NORBORNENE-BASED MONOMER HAVING HALOGEN GROUP CAPABLE OF INDUCING RADICAL POLYMERIZATION AT ITS TERMINAL, NORBORNENE POLYMER HAVING GROUP CAPABLE OF INDUCING RADICAL POLYMERIZATION AT SIDE CHAIN AND NORBORNENE POLYMER PRODUCED BY GRAFT REACTION OF THE MACROMONOMER USING ACRYLATE MONOMER OR STYRENE MONOMER, AND METHOD FOR PRODUCING THEM

摘要

PROBLEM TO BE SOLVED: To provide a polymer material having an excellent optical and mechanical properties by a ring-opening metathesis polymerization of a norbornene derivative containing a functional group. SOLUTION: The norbornene polymer is a derivative of a norbornene monomer having a halogen group capable of inducing a radical polymerization at its terminal and is produced by a ring opening metathesis polymerization of the monomer using a Ru-carbon-olefin coordination catalyst; äCl2Ru(CHPh)[P(C6H11)3]2}, and the norbornene polymer having at its terminal a group which can induce a radical polymerization is used for synthesizing the macromonomer. COPYRIGHT: (C)2005,JPO&NCIPI