| 摘要 |
A process is provided for the production of sulfur dioxide by combustion of sulfur and pure oxygen in a closed system that produces a high yield in the recovery of SO2 and that reduces environmental contamination to levels below the standard requirements. The pure oxygen is diluted before combustion in recirculated combustion gas that has been previously cooled, in order to maintain combustion at less than 1200 DEG C. The combustion gas is cooled, purified and liquefied, with the non-liquefied gas being recirculated in a closed system. A combustion gas having a high SO2 content, for example 84% SO2 (v/v), can thus be obtained, which is easily liquefied to a high SO2 recovery efficiency, for example 95% at -10 DEG C. Preferably, sulfur (1) is smelted in heat interchanger (3) and burned with oxygen (2) in combustion chamber of boiler (4). The combustion gas driven by suction from blower (7) is cooled by heat interchanger (5) and purifier/cooler (6). At fork point (8) a portion of the gas is recirculated to mixing point (9), where the pure oxygen (2) is incorporated. The remaining portion of the gas is liquified in cooling plant (10) to form liquid sulfur dioxide (11), leaving a non-condensable gaseous mix that is returned to the circuit via mixing point (12). <IMAGE> |
